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71.

The temperature distribution at depth is a key variable when assessing the potential of a supercritical geothermal resource as well as a conventional geothermal resource. Data-driven estimation by a machine-learning approach is a promising way to estimate temperature distributions at depth in geothermal fields. In this study, we developed two methodologies—one based on Bayesian estimation and the other on neural networks—to estimate temperature distributions in geothermal fields. These methodologies can be used to supplement existing temperature logs, by estimating temperature distributions in unexplored regions of the subsurface, based on electrical resistivity data, observed geological/mineralogical boundaries, and microseismic observations. We evaluated the accuracy and characteristics of these methodologies using a numerical model of the Kakkonda geothermal field, Japan, where a temperature above 500 °C was observed below a depth of about 3.7 km. When using geological and geophysical knowledge as prior information for the machine learning methods, the results demonstrate that the approaches can provide subsurface temperature estimates that are consistent with the temperature distribution given by the numerical model. Using a numerical model as a benchmark helps to understand the characteristics of the machine learning approaches and may help to identify ways of improving these methods.

  相似文献   
72.
Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH2I2, CH2ClI, CH3I, and C2H5I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C2H5I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO4 3? variation profile. Correlation between C2H5I and PO4 3? concentrations (r = 0.93) suggests that C2H5I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH2I2 and CH2ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).  相似文献   
73.
Urea is an unstable and intermediate organic nitrogenous compound present in coastal environments and is derived from the excretion of some aquatic organisms and wastewater discharges. Urea plays an important role in the nitrogen cycle, where it is utilized by algae, including diatoms. However, there are very limited relevant data on the production, consumption, and degradation of urea because of the lack of appropriate measurement techniques. The conventional method is based on the formation of a colored product when urea reacts with diacetyl monoxime in a sulfuric acid solution. We examined the optimal conditions for the formation of the colored product; specifically, we evaluated different temperatures (22–80 °C), reaction times, mixing ratios of color reagents, and sample storage times. Application of the single mixed color-developing reagent (COLDER) at 70 °C resulted in the optimal formation of the colored product within a short reaction time of 60 min. This method was then used to measure dissolved urea in different coastal environments. The concentrations detected were as follows: 0.65–0.72, 0.49–0.58, and 1.09–2.28 µM urea-N at coral reef, seagrass, and mangrove sites, respectively. Our results showed high precision (SD = 0.02, CV = 1.2%), a low detection limit (0.03 µM urea-N), and a high recovery rate (94–99%). In summary, this high-temperature procedure for urea measurements should be valuable for obtaining high-precision data that can further the understanding of urea dynamics and its role in coastal ecosystems.  相似文献   
74.
The influence of organic ligands on natural phytoplankton growth was investigated in high-nitrate low-chlorophyll (HNLC) waters and during a phytoplankton bloom induced by a mesoscale iron enrichment experiment (SEEDS II) in the western subarctic Pacific. The growth responses of the phytoplankton in the treatments with iron complexed with model ligand were compared with those with inorganic iron or a control. Desferrioxamine B and protoporphyrin IX were used as models for hydroxamate-type siderophore and tetrapyrrole-type cell breakdown ligand, respectively. In the HNLC water, iron associated with protoporphyrin IX especially stimulated smaller phytoplankton (<10 μm) growth, 1.5-fold more than did inorganic iron. Surprisingly, only the addition of protoporphyrin IX stimulated small phytoplankton growth, suggesting that these cell breakdown ligands might be more bioavailable for them. The protoporphyrin IX’s stimulatory effect on small phytoplankton was not observed during bloom decline phase. The growth of phytoplankton was inhibited in the treatment with desferrioxamine B-complexed iron, suggesting its low bioavailability for the natural phytoplankton community. Its inhibitory effects were particularly pronounced in pico-eukaryotic phytoplankton. During the iron-induced bloom, the phytoplankton’s iron-stress response gradually increased with the desferrioxamine B concentration, suggesting that the competition for iron complexation between natural ligands and desferrioxamine B affected phytoplankton growth. However, the pico-eukaryotes did seem better able to utilize the desferrioxamine B-complexed iron during the bloom-developing phase. These results indicate that the iron bioavailability for phytoplankton differs between bloom-developing and bloom-decline phases.  相似文献   
75.
The inner part of the Ariake Sea is one of the most productive estuarine systems in Japan. To examine potential food items for estuarine organisms, we conducted monthly observations of the dynamics of particulate organic matter along the macrotidal Chikugo River estuary in 2005 and 2006. In the neighboring macrotidal Midori and Kuma River estuaries, comparative observations were made. High turbidity and strong vertical mixing were observed only at low salinities (<10) in the Chikugo River estuary. In contrast, the Midori and Kuma River estuaries were characterized by less turbid and less mixed waters. Concentrations of particulate organic carbon often exceeded 5?mg?l?1 in or close to the estuarine turbidity maximum (ETM) of the Chikugo River estuary. However, such high concentrations were rarely observed in the other two estuaries. The observed differences could be attributable to different hydrodynamic processes related to the different lengths of tidal reaches: 23, 8, and 6?km in the Chikugo, Midori, and Kuma Rivers, respectively. In the Chikugo River estuary, spatiotemporal changes of chlorophyll a suggested that phytoplankton occurred abundantly up- and/or downstream from the ETM especially during the warm season. In contrast, pheophytin (i.e., plant detritus) always accumulated in or close to the ETM. Carbon stable isotope ratios and carbon to nitrogen ratios indicated that the plant detritus was derived from phytoplankton and terrestrial plants. The Chikugo River estuary has a high potential to support the production of estuarine organisms through abundant plant detritus in the well-developed ETM all the year round.  相似文献   
76.
Spectroscopic observations of OH airglow undertaken on May 2, 2006 at Uji, Japan reveal variations in intensity and rotational temperature related to the passage of an atmospheric gravity wave. The variations exhibit a period of approximately 1 h and magnitudes of 2–6% in intensity and 0.5–2% in rotational temperature. The vertical wavelength and intrinsic frequency of the atmospheric gravity wave were determined from the horizontal wavelength derived by an OH airglow imager, the background horizontal wind velocity obtained by the middle and upper atmosphere (MU) radar, and the dispersion relationship. The observed variations are consistent with the values calculated using the model of Liu, A.Z., Swenson, G.R. [2003. A modeling study of O2 and OH airglow perturbations induced by atmospheric gravity waves. J. Geophys. Res. 108 (No. D4), 4151. doi:10.1029/2002JD002474].  相似文献   
77.
A mammalian dentary discovered in the Coniacian Ashizawa Formation (Fukushima, northeastern Japan) is described. The specimen is a fragment of the horizontal ramus of a left edentulous dentary with five alveoli, the distal four of which are plugged with broken roots. Based on the morphologies of the dentary and the roots, it is considered to be of a therian mammal. This constitutes the first discovery of a Mesozoic mammal in northeastern Japan and highlights the potential for future mammal discoveries in the Cretaceous System in northeastern Japan, which will be significant for disclosure of the mammalian faunal evolution in East Asia during the Late Cretaceous.  相似文献   
78.
We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.  相似文献   
79.
The viscosity of a silicate melt of composition NaAlSi2O6 was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi2O6 melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 102 and 3.7 ± 0.5 × 102 kJ/mol at 2.2 and 2.9 GPa, respectively.  相似文献   
80.
We report on the ability for luxury Fe uptake and the potential for growth utilizing intracellular Fe pools for 4 coastal centric diatom isolates and in situ phytoplankton assemblages, mainly composed of diatoms. Iron uptake of the diatom isolates and natural phytoplankton assemblages in the Oyashio region during spring blooms were prevented by adding hydroxamate siderophore desferrioxamine B (DFB). After the addition of DFB, intracellular Fe in the diatom isolates supported 2.4–4.2 cell divisions with 1.2–2.6 Chl a doublings. The intracellular Fe was primarily used for cell generation rather than Chl a production, leading to a reduction in the Chl a cell quota in the Fe-starved cells with time. The metabolic properties of the Fe-starved cells with their cell morphologies were different among species or genera. An on-deck incubation experiment also exhibited 1.9 cell divisions and 0.81 Chl a doublings of phytoplankton after the addition of DFB, also indicating the preference of cell generation over Chl a production. A decrease in the level of cellular Chl a, a main light-harvesting pigment in Fe-starved diatoms, may become a superior survival strategy to protect the cells from high irradiance that can cause photo-oxidative damages through photosynthesis. Such relatively low-Fe with high-light conditions could often occur in surface waters of the Oyashio region from spring to summer.  相似文献   
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